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The (partial) replacement of synthetic polymers with bioplastics is due to increased production of conventional packaging plastics causing for severe environmental pollution with plastics waste. The bioplastics, however, represent complex mixtures of known and unknown (bio)polymers, fillers, plasticizers, stabilizers, flame retardant, pigments, antioxidants, hydrophobic polymers such as poly(lactic acid), polyethylene, polyesters, glycol, or poly(butylene succinate), and little is known of their chemical safety for both the environment and the human health. Polymerization reactions of bioplastics can produce no intentionally added chemicals to the bulk material, which could be toxic, as well. When polymers are used to food packing, then the latter chemicals could also migrate from the polymer to food. This fact compromises the safety for consumers, as well. The scarce data on chemical safety of bioplastics makes a gap in knowledge of their toxicity to humans and environment. Thus, development of exact analytical protocols for determining chemicals of bioplastics in environmental and food samples as well as packing polymers can only provide warrant for reliable conclusive evidence of their safety for both the human health and the environment. The task is compulsory according to legislation Directives valid to environmental protection, food control, and assessment of the risk to human health. The quantitative and structural determination of analytes is primary research task of analysis of polymers. The methods of mass spectrometry are fruitfully used for these purposes. Methodological development of exact analytical mass spectrometric tools for reliable structural analysis of bioplastics only guarantees their safety, efficacy, and quality to both humans and environment. This study, first, highlights innovative stochastic dynamics equations processing exactly mass spectrometric measurands and, thus, producing exact analyte quantification and 3D molecular and electronic structural analyses. There are determined synthetic polymers such as poly(ethylenglycol), poly(propylene glycol), and polyisoprene as well as biopolymers in bags for foodstuffs made from renewable cellulose and starch, and containing, in total within the 20,416–17,495 chemicals per sample of the composite biopolymers. Advantages of complementary employment in mass spectrometric methods and Fourier transform infrared spectroscopy is highlighted. The study utilizes ultra-high resolution electrospray ionization mass spectrometric and Fourier transform infrared spectroscopic data on biodegradable plastics bags for foodstuffs; high accuracy quantum chemical static methods, molecular dynamics; and chemometrics. There is achieved method performance |r| = 0.99981 determining poly(propylene glycol) in bag for foodstuff containing 20,416 species and using stochastic dynamics mass spectrometric formulas. The results highlight their great capability and applicability to the analytical science as well as relevance to both the fundamental research and to the industry.
Seasonal dynamics of trace metal concentrations and hydrological parameters in the Balu River, Bangladesh
Vol 5, Issue 2, 2024
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Abstract
This study investigates the seasonal dynamics of trace metal concentrations and hydrological parameters in the Balu River, Bangladesh, to inform sustainable water management practices and support efforts to meet environmental standards. Water level, discharge, rainfall, and groundwater data were collected from February to August 2019, alongside sediment samples analyzed for Zn, Pb, Cu, Cr, and Cd concentrations. Statistical analyses, including correlation studies, time series modeling, and Kolmogorov-Smirnov tests, revealed significant seasonal variations. Water levels and discharge rates increased dramatically during the wet season, with upstream levels rising by 862.68% and downstream by 752.92%. Trace metal concentrations showed diverse responses: Cd increased by 554.52%, Zn by 11.86%, while Pb, Cu, and Cr decreased by 44.15%, 5.16%, and 32.72% respectively. Strong correlations were observed between certain metals, particularly in wet periods, with notable relationships between Cr-Cu (r = 0.870) and Zn-Cr (r = 0.742). The integrated analysis of hydrological parameters and metal concentrations, using Gower coefficient and partial correlation analyses, suggests complex interactions between seasonal changes and pollutant dynamics. These findings highlight the need for season-specific water management strategies and more frequent monitoring to better understand and mitigate the environmental impacts of trace metal pollution in the Balu River system. The study contributes valuable insights into the interplay between hydrological conditions and trace metal behavior, essential for developing effective pollution control measures and achieving sustainable river management in Bangladesh.
Keywords
References
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